Heterogeneous Diffusion in Highly Supercooled Liquids
نویسندگان
چکیده
منابع مشابه
Spatially heterogeneous dynamics in supercooled liquids.
Although it has long been recognized that dynamics in supercooled liquids might be spatially heterogeneous, only in the past few years has clear evidence emerged to support this view. As a liquid is cooled far below its melting point, dynamics in some regions of the sample can be orders of magnitude faster than dynamics in other regions only a few nanometers away. In this review, the experiment...
متن کاملShear Viscosity and Diffusion in Supercooled Liquids
Under normal liquid conditions (at equilibrium or when moderately super cooled), molecular rotational and translational diffusion adhere closely to the sim ple Stokes-Einstein-Debye hydrodynamic model. Deeply supercooled "fragile" liquids present a striking exception, with translational diffusion alone occurring up to 102 — 103 times "too fast". This anomaly rests upon the statistics of fluct...
متن کاملDynamics of Highly Supercooled Liquids far
We rst review our recent simulation work on dynamic heterogeneity and supercooled liquid rheology. We then treat a supercooled polymer melt to study the stress relaxation function, transient stress evolution, shear-thinning, and elongation of chains.
متن کاملFrom cage-jump motion to macroscopic diffusion in supercooled liquids.
The evaluation of the long term stability of a material requires the estimation of its long-time dynamics. For amorphous materials such as structural glasses, it has proven difficult to predict the long-time dynamics starting from static measurements. Here we consider how long one needs to monitor the dynamics of a structural glass to predict its long-time features. We present a detailed charac...
متن کاملPressure dependence of diffusion in simple glasses and supercooled liquids.
Using molecular dynamics simulation, we have calculated the pressure dependence of the diffusion coefficient in a binary Lennard-Jones glass. We observe four temperature regimes. The apparent activation volume drops from high values in the hot liquid to a plateau value. Near the critical temperature of the mode coupling theory it rises steeply, but in the glassy state we find again small values...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Review Letters
سال: 1998
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.81.4915